| 1992 |
First Lady of France Danielle Mitterrand |
| 1995 |
Maria Oleksy, the wife of the Prime Minister of the Republic of Poland Józef Oleksy |
| 1997 |
Maria Oleksy, the wife of the Prime Minister of the Republic of Poland Józef Oleksy |
| 2003 |
First Lady of the Republic of Poland Jolanta Kwaśniewska |
| 2006 |
First Lady of the Republic of Poland Maria Kaczyńska and the First Lady of Ukraine Kateryna Juszczenko |
| 2006 |
Maria Oleksy, the wife of the Prime Minister of the Republic of Poland Józef Oleksy |
| 2008 |
First Lady of Slovakia Silvia Gasparovicova |
| 2008 |
First Lady of the Republic of Poland Maria Kaczyńska and the First Lady of Azerbaijan Mehriban Alijewa |
| 2010 |
First Lady the Republic of Poland Anna Komorowska and the First Lady of Russia Swietłana Miedwiediewa |
| 2014 |
First Lady of the Republic of Estonia Evelin Ilves |